EX Survival mode:
To unlock EX Survival mode, win ten battles in Survival mode.
Karakura Heroes match:
To unlock the Karakura Heroes match, beat all twenty Story missions under the Mission Battle option.
Bonus characters:
Unlock the following characters by performing the corresponding tasks:
Byakuya Bankai – Beat Story Mission 17.
Hisagi Shuuhei – Beat Time Attack mode with Komamura Sajin.
Hitsugaya Bankai – Beat Story Mission 9.
Ise Nanao – Beat Time Attack mode with Kyouraku Shunsui.
Ishida Quincy Final Stage – Beat Story Mission 6.
Komamura Sajin – Beat Time Attack mode with Yamamoto Genryuusai Shigekuni.
Kurotsuchi Nemu – Beat Time Attack mode with Kurotsuchi Mayuri.
Kusajishi Yachiru – Beat Time Attack mode with Zaraki Kenpachi.
Kyouraku Shunsui – Beat Time Attack mode with Ukitake Jyuushirou.
Renji Bankai – Beat Story Mission 12.
Rukia Shinigami – Beat Time Attack mode with Kuchiki Rukia.
Ulquiorra – Beat the Karakura Heroes match.
Extra partners:
Play Soul Road on the Normal or Hard difficulty setting with the specified character. When a question is answered correctly, the answer will be the name of the character that is unlocked. You must hit the blue spot with at least 60% Trust so that the question appears:
Hanatarou – Play as Ichigo or Bankai Ichigo
Iba Tetsuzaemon – Play as Rangiku
Ikkaku – Play as Renji or Bankai Renji
Isane – Play as Hinamori
Isshin – Play as Chad
Karin – Play as Chad
Keigo – Play as Ichigo or Bankai Ichigo
Kojima Mizuiro – Play as Ichigo or Bankai Ichigo
Kon – Play as Rukia or Shinigami Rukia
Kuukaku – Play as Yoruichi
Tousen – Play as Gin
Unohana – Play as Ishida or Final State Quincy Ishida
Ururu – Play as Urahana
Yumichika – Play as Kenpachi
Yuzu – Play as Urahana