Unlockable Characters:
Cao Cao – Complete Musou Mode with 3 Wei characters
Cao Pi – Deafeat Cao Pi within 5 minutes on Wu side of He Fei
Cao Ren – Succeed in Battle Objective 2 on the Lu Bu side of Fan Castle
Diao Chan – Complete Musou Mode with 1 character from each Kingdom
Dong Zhuo – Complete Musou Mode with Lu Bu
Gan Ning – Complete Musou Mode with 1 Wu character
Guan Ping – Succeed in 2 battle objectives on the Shu side of Fan Castle and finish battle with Guan Ping alive
Huang Gai – Succeed in Battle Objective 3 on the Wu side of The Battle of Chi Bi
Huang Zhong – Succeed in 1 battle objective on the Wei side of Ding Jun Mountain
Liu Bei – Complete Musou Mode with 3 Shu characters
Lu Bu – Complete Musou Mode with Liu Bei, Cao Cao, and Sun Jian
Lu Meng – Succeed in 2 battle objectives on the Wei side of He Fei
Ma Chao – Succeed in 2 battle objectives on the Wei side of Han Zhong Attack Defense Battle
Pang Tong – Succeed in 3 battle objectives at Cheng Du battle and finish battle with Pang Tong alive
Sun Ce – Succeed in Battle Objective 1 on the Sun Jian side of the Battle of Xia Pi
Sun Jian – Complete Musou Mode with 3 Wu characters
Sun Quan – Succeed in Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi
Wei Yan – Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive
Xiahou Yuan – Succeed in 1 battle objective on the Shu side of Ding Jun Mountain
Xiao Quio – Succeed in Battle Objective 3 on the Wu side of the Battle of Shi Ting
Xu Chu – He Fei, Wu side, Personally kill Cao Ren and Xu Chu
Xu Huang – Succeed in 2 battle objectives on the Wei/Wu side of Fan Castle
Yuan Shao – As Wei, complete all 3 targets and capture Wu Chao before completing the stage.
Yue Ying – Succeed in Battle Objective 1 on the Wei side of the Battle of Wu Zhang Plains
Zhang Liao – Complete Musou Mode with 1 Wei character
Zheng He – Succeed in 2 battle objectives on the Shu side of Han Zhong Attack Defense Battle
Zhou Tai – Succeed in 3 battle objectives on the Shu side of Yi Ling
Zhuge Liang – Complete Musou Mode with 1 Shu character
Unlockables:
Very Hard Difficulty – Complete Musou Mode with any character.
Unlock Chaos Difficulty – Complete Musou Mode with a character from Wu, Shu, or Wei.
Master Difficulty – Beat any musou mode on Easy or Normal.
Hell Difficulty – Beat Wei, Wu, or Shu.
Alternate Costumes – Reach level 25 with any character.
Voice Gallery – Reach level 50 with any character.
Movie Player – Complete Musou mode.